To make that pipe fit, try making a 1/8 to 1/4 wide cut next to the collector, then closing the gap and rewelding it closed. You may need to make a couple cuts and welds to get the angle change your looking for. I can't image that this would change anything on your performance levels, after all it first needs to fit. You could also try an angled cut across the pipe, rotate the pipe 180 degrees and weld it back together, same effect as pinch welding noted earlier.... Do take time on your metal work here so that the pieces fit closely together before attempting to weld it all back together. You can change the size of the cut ends with the same pinch welding process to get the fit right before burning it all in. A die grinder will help you get rid of the Frankenstein appearances when you done. Just take your time. Good luck.