Did you spend much time trying to get all of the mill scale off before priming? And did you use a flap disk, wire brush or what? I'm getting close to the painting stage with our Tarantula. My metal is pretty filthy from whatever mill processes were used.
Your frame looks incredible. We are going to go with metallic Green or Red.
The metallic colors look cool. Red would be sweet, I didn't see the green at our local Home Depot.
I didn't spend a lot of time cleaning the metal. I just quickly went over it with a flap disc. They are great for grinding, blending and cleaning. Then I wiped it down with some Simple Green to clean off the remainder of dirt. I sprayed one coat Rustoleum Self Etching Primer first, then a coat of Rustoleum Metal Primer in white, then the blue metallic. I'll put a clear coat on before I'm done.
It's overkill for a rattle can job on a go-kart that's going to get banged around, but we have nothing else to do while waiting on parts to get here. Against Mom's wishes I let the boy paint a tiny bit; his hands are not big enough to use a spray paint can so he only did a small section just to say he helped.

Goodluck with the project!
Good job. How much does it weigh?