4 out of 5 times that I think my rim is bent, it ended up being the axle itself is bent, not the rim
Run the axle nut up close to the wheel but not tight. Run the kart SLOWLY a few feet until hopefully the wheel will "pop" loose. Once it does you can jack up the kart and remove the seized wheel.
I had a really rusted and cracked rim on my Kilowatt a while back. I couldn't get anything to work so I borrowed a buddies plasma cutter, let all the air out of the tire and cut the rim off the axle around the hub. Then I used a air grinder to cut a groove in the hub (without touching the axle), heated it up red hot and pounded the hub off with a long steel rod from the backside. I had pictures and videos but have since lost them.
Here is my new rim but I drew a line around the hub where I plasma torched it off. It worked perfectly but not everyone has access to nice equipment
I would still put some cutting fluid on the bits to keep them sharp.
Have you seen the cutting wax you can get? I think it's more designed for stainless/aluminum but man that stuff works well!