depends on the motors in question..
but sure if the total power to weight ratio is better,
then that's the better solution.
That not only includes the battery though, difference in motor weight also has to be taken into account, I doubt the controller weight difference will matter much tbh, so we'll leave that aside.
But what about ride time?
I mean sure you add batteries,
but you do NOT add capacity at all
assuming 45Ah batteries for example
you'll have 60V 45Ah on and 2kW (for ease of calc assuming that's electric power)
so max ride time on full power ~1:21h
with a 3kW Motor
you still have just 45Ah (this time @72V) but drain 3kW
and you reduce the ride time to ~1:04 h
And since you cannot completely drain a battery without destroying it....
that's even 20% less really 1:04h for the 60V 2KW motor and just 51mins for the 72V 3kW version
depending on the battery sizes, you might drop below your required ride time
'sid