A big point on safety would be, Acetylene ON first, Acetylene OFF first.
So if you want to cut, A(gas) on, Light, adjust o2 for cutting. Shut down, A(gas) off, Turn off O2.
If the O2 is turned off first, there is a potential for the gas(acetylene) while on fire to burn down the O2 hose to the cylinders, this is called a Flash back.
Most O/A setups has dual flashback arrestors and check valves so this is mostly prevented, but still the principal applies. At the welding school I had attended, they had drilled this into our heads about this, so Im passing this on to someone else.
Oh and another thing, it may seem stupid but time and time again I see this and just cringe..... dont cut over your hose lines, be mindful about where they are at all times. Dangerous things can arise.